Loading...
Projects / Programmes source: ARIS

Chemical interaction of low pressure oxygen and hydrogen plasma with solid surfaces.

Research activity

Code Science Field Subfield
2.09.02  Engineering sciences and technologies  Electronic components and technologies  Electronic components 
Keywords
electric discharges, RF radiofrequency discharges, hydrogen plasma, H-plasma interaction with surface, oxygen plasma, O-plasma interaction with surface, surface cleaning, plasma cleaning, surface activation, catalytic probes, nickel catalytic probes, Langmuir probes
Evaluation (rules)
source: COBISS
Researchers (10)
no. Code Name and surname Research area Role Period No. of publicationsNo. of publications
1.  01694  Zlatko Bele  Electronic components and technologies  Researcher  1997 - 1999  17 
2.  05640  MSc Brane Kren  Electronic components and technologies  Researcher  1997 - 1999  15 
3.  10429  PhD Miran Mozetič  Electronic components and technologies  Researcher  1997 - 1999  1,353 
4.  09619  Karol Požun  Electronic components and technologies  Researcher  1997 - 1999  56 
5.  09105  Borut Praček  Electronic components and technologies  Researcher  1997 - 1999  113 
6.  05647  PhD Rudolf Ročak  Electronic components and technologies  Head  1997 - 1999  20 
7.  10497  MSc Sonja Spruk  Electronic components and technologies  Researcher  1997 - 1999  29 
8.  13059  Miroslav Stipančič  Electronic components and technologies  Researcher  1999 
9.  01718  PhD Iztok Šorli  Electronic components and technologies  Researcher  1997 - 1999  63 
10.  01741  PhD Anton Zalar  Electronic components and technologies  Researcher  1998 - 1999  383 
Organisations (1)
no. Code Research organisation City Registration number No. of publicationsNo. of publications
1.  0341  MIKROIKS, microelectronics engineering, consulting and service  Ljubljana  5286646  70 
Abstract
Interaction of low pressure weakly ionized hydrogen and oxygen plasma with solid surfaces will be studied. Plasma parameters will be measured with Langmuir and catalytic probes, while the surface phenomena will be determined with AES, ESCA, SEXAFS, SEM, alpha step and paint test. A new type of catalytic probe for measurement of H density in highly dissociated plasma and in gaps between samples will be constructed and tested. Quantitative data on the rate of reduction of thin oxide layers on metal samples versus plasma parameters will be obtained. The rate of low temperature oxidation of plastic materials exposed to oxygen plasma will be determined and the resultant improved paintability, wettability and adhesion will be tested. Discharge cleaning is nowadays widely used in different industrial processes. It is gradually replacing classical wet chemical cleaning, since wet cleaning often leads to poor cleanliness of surfaces, and because of ecological reasons. The side product of wet cleaning is a large quantity of used chemicals, which often cannot be recycled, while environmental pleasant destruction of the chemicals is expensive. The best exchange for wet chemical cleaning is the use of a plasma of reactive gases. Organic impurities are effectively removed by oxygen plasma, while oxide impurities are reduced by hydrogen plasma. Interaction of reactive particles, produced in hydrogen and oxygen plasma, with solid surfaces, is still not well described. In particular, there is a shortage of quantitative data on the rate of removal of impurities as a function of the flow of reactive particles onto a surface. Results of sample treatment in plasma are often expressed in the terms of some characteristic of a material being treated, such as surface energy, adhesion, wettability, contact resistance, etc. The subject of the proposed research is the role of plasma parameters on chemical reactions on solid surfaces. Plasma parameters will be measured with different Langmuir probes, and a specially constructed catalytic probe, which will allow for the determination of the density of chemical reactive neutral particles in the vicinity of samples. Reactions on surfaces will be monitored with the AES, ESCA and SEXAFS, while the results of plasma treatment of samples will be controlled with the Alpha step method, SEM and wettability test. The rate of reduction of metal oxide thin layers, as a function of the thickness of the oxide layer and the flow of neutral hydrogen atoms on surfaces, will be determined. The result of the investigation of interaction of oxygen plasma with organic materials will be the determination of the rate of oxidation as a function of the density of oxygen ions and neutral atoms in the vicinity of samples. Proposed investigations will give us a basic knowledge needed for development of technologies of discharge cleaning, which Slovenian industry will have to introduced in the next years in order to fulfill severe ecological rules already effective in the EC countries.
Views history
Favourite