Projects / Programmes
Metal-decorated ZnO for photocatalytic removal of emerging pharmaceutical contaminants
Code |
Science |
Field |
Subfield |
1.04.03 |
Natural sciences and mathematics |
Chemistry |
Inorganic chemistry |
Code |
Science |
Field |
1.04 |
Natural Sciences |
Chemical sciences |
Photocatalyst, nanomaterials, water purification, surface modification, flow reactor, mechanism of action
Researchers (7)
Organisations (2)
Abstract
Project abstract Nowadays, pollution of waters has unambiguously been recognized as a threat not only for human health but also to the environment and especially the quality of living of future generations. One of the major threats to surface and ground water systems are the so called emerging pharmaceutical contaminants (EPCs); they enter the environment through the production line or through leaching from commercial products and their domestic (over)use. Their presence, even at low concentrations, is responsible for variety of environmental problems including toxicity, endocrine disruption, decrease in microflora diversity and – in the case of antibiotics – the rise in antibiotic-resistant bacteria. Studies have shown that conventional mechanical, chemical, biological and physical wastewater treatment methods (or a combination of these) are incapable of removing the majority of these emerging compounds. On the other hand, non-selective and highly potent hydroxyl radicals generated from photocatalytic processes can remove even the most persistent organic compounds (including pharmaceuticals). However, conventional catalysts such as TiO2, ZnO, CdS still need to be optimized and modified in some way, due to their inherent relatively high rate of recombination, slow mobility of electrons and holes and/or photo-corrosion. This project will deliver first colloidal ZnO nanoparticles ready for immediate use as catalysts or further modification; second surface-modified ZnO with transition metals which will improve charge carrier separation and improve their function under visible light; third mechanically stable films of such catalysts, coated on foamed alumina that will be employed to treat pharmaceuticals of emerging concern in a small-scale flow-through photocatalytic reactor. Also, parameters that affect the efficiency of the catalysts, their mechanical robustness and their mechanisms of action will all be explored in the scope of the project.
Most important scientific results
Interim report
Most important socioeconomically and culturally relevant results