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Projects / Programmes source: ARIS

Development of the methods for determination of fluoride in food, organic matter and soil

Research activity

Code Science Field Subfield
1.04.00  Natural sciences and mathematics  Chemistry   

Code Science Field
P300  Natural sciences and mathematics  Analytical chemistry 
Keywords
diet, organic matter, soil, fluoride, decomposition, determination, fluoride ion selective electrode, validation
Evaluation (rules)
source: COBISS
Researchers (2)
no. Code Name and surname Research area Role Period No. of publicationsNo. of publications
1.  18457  PhD Maja Ponikvar Svet  Chemistry  Researcher  2004 - 2006  215 
2.  01063  PhD Boris Žemva  Chemistry  Head  2004 - 2006  597 
Organisations (1)
no. Code Research organisation City Registration number No. of publicationsNo. of publications
1.  0106  Jožef Stefan Institute  Ljubljana  5051606000  90,753 
Abstract
The content of fluoride in drinking water can be determined directly as a free fluoride by a fluoride ion selective electrode. On the other hand, total decomposition of the sample is prerequisite for the determination of fluoride in food and other organic matter. Total decomposition during which complex fluoride is transformed into water-soluble ionic form is a critical step of the entire analytical procedure. Due to analytical unreliability a large part of existing data on fluoride in biological samples should be regarded by skepticism and is accordingly of limited value since only a few studies report use of certified reference materials (CRM's) as a part of the quality assurance system. Increasing awareness of food as a possible source of fluoride has accentuated the need not only to re-establish the credibility of fluoride analysis by generating accurate data but also the need for more appropriate analytical procedures. A new approach to total decomposition and subsequent determination of total fluoride by using a fluoride ion selective electrode in food and organic matter will be developed and validated using CRM's. The content of fluoride in total diet samples of Slovenian army will be determined by the developed method what will enable to assess the daily intake of fluoride. A method for determination of fluoride in soil will be validated. By using developed methods the contents of fluoride in vegetation and soil from fluoride "clean" and fluoride "polluted" environment will be assessed. Possible accumulation and effects of fluoride on vegetation and soil in the surrounding of fluoride releasing industry in Slovenia will be estimated.
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