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Projects / Programmes source: ARIS

Sinteze in transformacije organskih spojin. Novi reagenti v organski sintezi. Stereoselektivne in regioselektivne sinteze aminokislin, (Slovene)

Research activity

Code Science Field Subfield
1.04.04  Natural sciences and mathematics  Chemistry  Organic chemistry 

Code Science Field
P390  Natural sciences and mathematics  Organic chemistry 
Keywords
organic chemistry, heterocyclic chemistry, 1,3-dipolar cycloadditions, stereoselective synthesis, regioselective synthesis, 2,2-disubstituted ethenylamino-3-dimethylaminopropenoates, 2-acylamino-3-cyanopropenoates, C-nucleosides, heterocyclic polyols, chiral azomethine imines.
Evaluation (rules)
source: COBISS
Researchers (12)
no. Code Name and surname Research area Role Period No. of publicationsNo. of publications
1.  16336  PhD Urška Bratušek  Chemistry  Researcher  1996 - 2001  32 
2.  18867  PhD Lucija Jukić Soršak  Chemistry  Researcher  1996 - 2001  31 
3.  17138  Zdenka Kadunc    Researcher  1998 - 2001 
4.  17139  Marjeta Katarin Kastelic    Researcher  1998 - 2001 
5.  17140  Tončka Kozamernik-Hudeček    Researcher  1998 - 2001 
6.  19527  Irena Povalej    Researcher  2000 - 2001 
7.  19114  PhD Simon Rečnik  Chemistry  Researcher  1996 - 2001  78 
8.  15558  PhD Gorazd Soršak  Chemistry  Researcher  1998 - 2001  36 
9.  00868  PhD Branko Stanovnik  Chemistry  Head  1996 - 2001  1,884 
10.  08284  PhD Jurij Svete  Chemistry  Researcher  1999 - 2001  931 
11.  17142  Tatjana Toporiš Stipanovič    Researcher  1998 - 2001 
12.  15168  PhD Cvetka Turk Jančigaj  Chemistry  Researcher  1996 - 2001  30 
Organisations (1)
no. Code Research organisation City Registration number No. of publicationsNo. of publications
1.  0103  University of Ljubljana, Faculty of Chemistry and Chemical Technology  Ljubljana  1626990  23,426 
Abstract
This research project is dealing with: the syntheses and transformations of 2,2-disubstituted ethenylamino-3-dimethylaminopropenoates , 2-acylamino-3-cyanopropenoates and realted compounds as versatile reagents for the preparation of various heterocyclic systems, such as furans, pyrrols, pyrazoles, imidazoles, piridines, pyridazines, pyrimidines and their fused analogs. The intention is the development of general methods and reagents, selectivity and regioselectivity of chiral dimethylaminopropenoates, azomethine imines and analogs as building blocks in the synthesis of complex chiral molecules. We can introduce with them also a protected amino or hydroxy group, since the protecting group can be easily removed. They open an easy access to several natural products, such as aplysinopsins and azaaplysinopsins. The syntheses of chiral heterocyclic compounds are dealing with the syntheses and transformations of heteroarilalanines, C-nucleosides and polyhydroxy heterocyclic systems, pyrazolo/1,2-a/pyrazoles and stereoselective 1,3-dipolar cycloadditions of diazolakanes, nitril oxides, nitril imines and azomethine imines to unsaturated and heterocyclic systems.
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