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Organometallic compounds of the group 4 elements (Ti, Zr, Hf) with fluorides and quinolones

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Research activity

Code Science Field Subfield
1.04.03  Natural sciences and mathematics  Chemistry  Inorganic chemistry 

Code Science Field
P003  Natural sciences and mathematics  Chemistry 
P351  Natural sciences and mathematics  Structure chemistry 
Keywords
Lithium fluoride, X-ray structure analysis, pentamethycyclopentadienyl, NMR spectroscopy, calcium fluoride, hexamethyphophortriamide, organofluorotitanate, lanthanum
Evaluation (rules)
source: COBISS
Citations Citations for bibliographic records in COBIB.SI that are linked to records in citation databases
source: WoS source: Scopus source: COBISS
Researchers (4)
no. Code Name and surname Research area Role Period No. of publications
1.  07512  PhD Alojz Demšar  Natural sciences and mathematics  Principal Researcher  1998 - 1999  265 
2.  03374  PhD Ivan Leban  Natural sciences and mathematics  Researcher  1998 - 1999  539 
3.  08525  PhD Saša Petriček  Natural sciences and mathematics  Researcher  1997 - 1999  185 
4.  11053  PhD Iztok Turel  Natural sciences and mathematics  Researcher  1997 - 1999  571 
Organisations (1)
no. Code Research organisation City Registration number No. of publications
1.  0103  University of Ljubljana, Faculty of Chemistry and Chemical Technology  Ljubljana  1626990  22,058 
Abstract
Lithium fluoride, prepared in situ from lithium chloride and trimethytin fluoride, reacts with organotitanium fluoride, giving the first soluble lithium fluoride derivat. In the solid state, according to the X-ray structure analysis, lithium is coordinated by four fluorine atoms. The solubility is provided by pentamethycyclopentadienyl ligads bonded to the titanium atoms. In the solution a dissociation equilibrium exists which was characterised by NMR spectroscopy and the thermodynamic parameters were determinated. Organofluorotitanoxanes react with trialkyl- in triarylaluminijem with the substitution of of fluorine atoms by organic groups. The prepared compounds were characterised by NMR and IR spectroscopy and X-ray crystal structure analysis. Calcium fluoride, prepared in situ, reacts with organotitanium fluoride. Calcium atom in the products is coordinated by eight fluorine atoomsand is coordinativelly unsaturated. It reacts with hexamethyphophortriamide, tetrahydrofuran giving adducts as well as interacts with chloroform as determined by NMR spectroscopy and X-ray structural analysis. Lutidinium organofluorotitanate was prepared by the reaction of lutidinium-hydrogen fluoride adduct and organotitanonium fluoride. It reacts with lanthanum trifluoromethansulfonate and strontium iodide respectively giving the compounds with lanthan and strontum atom in the fluorine environment of the molecular compound. The compounds were charactrerised by spectroscopic and diffraction methods.
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