Projects / Programmes source: ARIS

Mechanisms of polymerization of aniline

Research activity

Code Science Field Subfield
1.04.02  Natural sciences and mathematics  Chemistry  Structural chemistry 

Code Science Field
P351  Natural sciences and mathematics  Structure chemistry 
Polyaniline, Structure of Polyaniline, Electrical Conductivity
Evaluation (rules)
source: COBISS
Researchers (5)
no. Code Name and surname Research area Role Period No. of publicationsNo. of publications
1.  14126  PhD Matjaž Krajnc  Chemical engineering  Head  1998 - 1999 
2.  17269  Janez Malovrh    Researcher  1998 - 1999 
3.  12041  PhD Ida Poljanšek  Chemical engineering  Researcher  1998 - 1999 
4.  05018  PhD Anton Šebenik  Materials science and technology  Researcher  1998 - 1999 
5.  17272  Mirjana Širca    Researcher  1998 - 1999 
Organisations (2)
no. Code Research organisation City Registration number No. of publicationsNo. of publications
1.  0103  University of Ljubljana, Faculty of Chemistry and Chemical Technology  Ljubljana  1626990 
2.  0104  National Institute of Chemistry  Ljubljana  5051592000 
Polyaniline consists of three basic units, e.g. completely reduced leucoemeraldine base, partly oxidised emeraldine base and completely oxidised pernigraniline base. Beside these, some defective structures can be formed which influence the molecular weight, the electrical conductivity, the solubility and the formation of film. The properties of polyanilines depend on the share of individual units and theirs sequence distribution in the chains. The possibility of the formation of film depends mostly on the quantity of the emeraldine base. In this work, the influence of polymerization conditions, transformation into individual chemical form and doping technique on the structure and electrical conductivity of polyanilines will be systematically investigated using 600 MHz high power solution and solid state multinuclear one and two dimensional NMR spectroscopy and impendance spectroscopy.
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