The interaction between xylem phenology and climate assesses forest growth and productivity and carbon storage across biomes under changing environmental conditions. We tested the hypothesis that patterns of wood formation are maintained unaltered despite the temperature changes across cold ecosystems. The study included wood formation experiments in 10 conifer species from 39 sites in the Northern Hemisphere and covering an interval of mean annual temperature exceeding 14 K. The results showed that the phenological events and mean annual temperature of the sites were related linearly, with spring and autumnal events being separated by constant intervals across the range of temperature analysed. At increasing temperature, first enlarging, wall-thickening and mature tracheids appeared earlier, and last enlarging and wall-thickening tracheids occurred later. Overall, the period of wood formation lengthened linearly with the mean annual temperature, from 83.7 days at _2 °C to 178.1 days at 12 °C, at a rate of 6.5 days °C_1. April–May temperatures produced the best models predicting the dates of wood formation. Our findings demonstrated the uniformity of the process of wood formation and the importance of the environmental conditions occurring at the time of growth resumption. Under warming scenarios, the period of wood formation might lengthen synchronously in the cold biomes of the Northern Hemisphere.
COBISS.SI-ID: 2558089
The paper was published in the most prestigious scientific journal in the field “materials science, paper & wood” (SCI IF(2015) = 3.195; journal ranking in the field: 1/21). It was proven that spruce wood could be protected against brown rot and molds by making wood highly hydrophobic, with treatment in aqueous solution of octadecyltrichlorosilane (OTS). The consequences of this treatment were substantially lower water uptake and water vapour sorption, as well as increased dimensional stability.
COBISS.SI-ID: 2593417
Freeze dried nanofibrils were acetylated in a heterogeneous system with acetic anhydride, pyridine, and dimethylformamide and the obtained acetylated cellulose nanofibrils (CNFac) were combined with poly(lactic acid) (PLA) to a composite. CNFac with its partially hydrophobic surface showed a good compatibility with PLA resulting in composite films with improved properties. Tensile strength (TS), modulus of elasticity (MOE), and elongation at break (EB) of PLA/CNF increased significantly when 2%-5% of CNFac was added to the PLA matrix, while the addition of 10% and higher amounts CNFac decreased the EB at a higher TS and MOE. Mechanical parameters did not improve in the case of unmodified CNF addition. The addition of CNFac maintained transparency and had absorbance values between those of pure PLA film and PLA film with 2% CNF, while films formed with the addition of 5 and 10% of CNF were less transparent. The addition of CNF did not essentially affect the thermal properties of nanocomposite films. The addition of 2%-10% of CNFac increased the enthalpy and maximal temperature of cold crystallization as opposed to higher loading of CNFac. The results of differential scanning calorimetry (DSC) coincide with those of the mechanical properties. Tailoring properties of PLA/CNF are only reproducible in case of homogenously distributed CNF within the PLA matrix and by an improved interphase adhesion between PLA and CNF
COBISS.SI-ID: 2670985
Water repellents, as environmentally-friendly treatments, are gaining popularity as non-biocidal solutions for wood protection. Drying oils, in addition to waxes and organosilicon compounds, are one of the most important water repellents for wood. Tung oil has so far been proven to be one of the best performing oils for wood protection. However, tung oil, similarly as other oils, does not penetrate deeply into wood, due to its high viscosity. In order to improve the penetration of oil into wood, a vacuum-pressure procedure has to be applied. The species used in this study are important in Central Europe: sweet chestnut heartwood (Castanea sativa), European larch heartwood (Larix decidua), Scots pine heartwood and sapwood (Pinus sylvestris) and Norway spruce (Picea abies). Oil uptake depends on the applied impregnation method and on the wood species used. Retention of tung oil was higher after an impregnation process than with the immersion procedure. Magnetic resonance imaging (MRI) was applied to elucidate the influence of wood species on oil penetration and distribution in wood after treatment. High spatial resolution MR imaging is highly sensitive to changes of liquids in wood and is therefore also very appropriate for monitoring oil penetration. Furthermore, with a good signal to noise ratio of MR images, the method can also discern among specimens with different patterns of oil distribution, as well as between areas of early-wood and late-wood
COBISS.SI-ID: 2685065
The use of wood in outdoor, above-ground applications is increasing in Europe. To further increase wood usage, more information related to service life and maintenance costs must be provided. Water exclusion efficacy (WEE) is one of the most important factors influencing service life and strongly correlates to wood moisture dynamics, surface properties, and hydrophobicity (WEE as a whole). WEE can be improved with modifications and hydrophobic treatments. The aim of this study was to elucidate which wood surface properties affect WEE and to note changes over time caused by artificial or natural aging. Wood samples of oak (Quercus), sweet chestnut (Castanea sativa), European larch (Larix decidua), Scots pine heartwood and sapwood (Pinus sylvestris), Norway spruce (Picea abies), and beech (Fagus sylvatica) were used to investigate this phenomenon. The moisture performance of the wood samples was improved with thermal modification, wax, oil, and biocide treatment. In total, 17 materials were prepared. After treatment, four different aging procedures were applied. Before and after aging, Fourier transform infrared spectra, colour, and contact angle were determined. The analysis of untreated wood based materials indicated that durability and hydrophobicity are related. Of all the treatments, wax performed the best and retained high hydrophobicity even after the most severe aging method (outdoor exposure).
COBISS.SI-ID: 2555017