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Projects / Programmes source: ARIS

Synthesis of alkali activated materials with microwave heating

Research activity

Code Science Field Subfield
2.01.00  Engineering sciences and technologies  Civil engineering   

Code Science Field
2.01  Engineering and Technology  Civil engineering 
Keywords
Slag, ash, metakaolin, alkali activation, microwave heating, nuclear magnetic resonance
Evaluation (rules)
source: COBISS
Points
5,257.29
A''
1,332.11
A'
2,792.21
A1/2
3,626.41
CI10
6,545
CImax
239
h10
42
A1
19.2
A3
6.78
Data for the last 5 years (citations for the last 10 years) on July 11, 2024; A3 for period 2018-2022
Data for ARIS tenders ( 04.04.2019 – Programme tender, archive )
Database Linked records Citations Pure citations Average pure citations
WoS  311  6,938  6,293  20.23 
Scopus  323  7,725  7,031  21.77 
Researchers (9)
no. Code Name and surname Research area Role Period No. of publicationsNo. of publications
1.  11292  PhD Vilma Ducman  Civil engineering  Researcher  2021 - 2024  510 
2.  30873  PhD Barbara Horvat  Materials science and technology  Head  2021 - 2024  118 
3.  35379  PhD Andraž Krajnc  Chemistry  Researcher  2021 - 2024  114 
4.  18146  PhD Gregor Mali  Physics  Researcher  2021 - 2023  384 
5.  24724  PhD Branka Mušič  Civil engineering  Researcher  2022 - 2024  123 
6.  52007  PhD Tia Kristian Tajnšek  Chemistry  Researcher  2022 - 2024  17 
7.  58093  Anže Tesovnik  Geology  Junior researcher  2023 - 2024  12 
8.  35338  PhD Katja Traven  Civil engineering  Researcher  2021 - 2022  71 
9.  20335  PhD Bojan Zajec  Civil engineering  Researcher  2021 - 2024  184 
Organisations (2)
no. Code Research organisation City Registration number No. of publicationsNo. of publications
1.  1502  Slovenian National Building and Civil Engineering Institute  Ljubljana  5866324000  10,214 
2.  0104  National Institute of Chemistry  Ljubljana  5051592000  21,227 
Abstract
Alkali activated materials (AAM) are a promising alternative to conventional building materials (cement, concrete, ceramics) because the energy required to produce AAM is lower, i.e. preparation time and temperature are lower, and consequently also carbon footprint [1,2]. Materials that can be used as precursors must contain sufficient amount of Si and Al in the amorphous phase and as few elements of group 1 as possible, which are added later with the alkali activator since the final ideal ratio of elements of group 1:Al:Si of all of the ingredients together is 1:1:1.9 [3]. The selected Al:Si ratio can be achieved by mixing the appropriate precursors. The most used precursor is metakaolin, which is considered as the standard in alkali activation [4]. While for alkali activator mostly used are NaOH, KOH, Na-water glass and Kwater glass. First phase of the reaction in the alkaline medium, dissolution of the precursor, is followed by the transport of the elements, alumosilicate monomers formation (binding of Al and Si with O into tetrahedra), polycondensation (and dehydration) into the alumosilicate network, which is mostly amorphous [5]. The first reaction phase is followed by the curing at low temperatures (below 100 ° C), i.e. further dehydration to the final product, i.e. AAM. AAM has already been implemented in real-life building industry in Australia, first for an airport runway in Brisbane [6], and then for a public building in Queensland [7]. The aim of this project is to test the influence of electromagnetic waves in the microwave spectrum on different phases of AAM synthesis, both initial, i.e. when microwaves volumetrically increase the temperature of the alkali activated mixture, thus speeding up the reaction, shortening the synthesis time and lowering the used energy [8], as well as in the later stages when microwaves affect dehydration (drying) and sintering. To achieve these goals, the project will focus on: - Chemical and mineralogical analysis of metakaolin, - Determination of the optimal mixture of precursor and alkali activators [9], - Selection of a microwave oven for synthesis of AAM and selection of suitable moulds that can be used in a microwave oven, - Optimization of variable parameters of microwaves at all stages of AAM synthesis to achieve optimal mechanical properties of AAM, - Implementation of the acquired knowledge with using waste material for the precursor. The project is divided into 5 work packages related to the specific project objectives which will be performed by ZAG - Department of Materials, KI – Department of Inorganic Chemistry and Technology. Both groups already have extensive experience in either preparation and charcterization of AAM from different precursors or analysis of materials with NMR . The acquired knowledge will be the basis for the development of various products with better mechanical properties, prepared in a shorter time with less invested energy. The project will thus provide new interdisciplinary knowledge that will combine technology and environmental aspects.
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